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Remote circuit diagram. Predict the number of unpaired electrons in cof63. Coordination compound coordination compound ligand field and molecular orbital theories. And show why it is a n acceptor ligand.
Log in join now 1. The six ligands can interact with the metal in a sigma or pi fashion. Since 1950 it has been apparent that a more complete theory which incorporates contributions from both ionic and covalent bonding is necessary to give an adequate account of the properties of coordination compounds.
2 draw the molecular orbital diagram for mo of conh33 why nh3 molecule is called a sigma donor ligand. Cobalt exists in the 3 oxidation state. Follow report by.
This is why there are 10 elements in each row of the d block. We now turn to a molecular orbital description of the bonding in ceo2. Fluorine ion is a weak ligand.
3 draw the molecular orbital diagram for mo of cof63. Such a theory is the so called ligand field theory lft which has its origin in the. The complex formation involves d orbitals of the outershell which give a high spin complex.
Log in join now secondary school. Smos for octahedral complexes 1. For a diatomic molecule the atomic orbitals of one atom are shown on the left and those of the other atom are shown on the right.
As a result the co3 ion will undergo sp3d2 hybridzation. 1 draw the molecular orbital diagram for mo theory of coco63. It cannot cause the pairing of the 3d electrons.
The relative energy levels of atomic and molecular orbitals are typically shown in a molecular orbital diagram figure 9. In the both of water and methane the centre atom is a sp 3 state but the shape of the two molecules are different because in methane all electron are shared with hydrogen and thus forming tetrahedral shape and water h 2 o a water molecule has two pairs of bonded electrons and two unshared lone pairs. It so happens that the molecular orbital description of this molecule provided an explanation for a long standing puzzle that could not be explained using other bonding models.
Hence it shows bent shape or v shape. Molecular oxygen is paramagnetic. For octahedral complexes the crystal field splitting diagram will have its eg orbitals above the t2g orbitals and is.
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